专利摘要:
1368416 Herbicidal 1,2,4-triazin-5-ones BAYER AG 17 May 1973 [18 May 1972] 23552/73 Heading C2C [Also in Division A5] 3 - Methyl - 4 - amino - 6 - phenyl - 1,2,4- triazin-5-one is obtained either by (a) reacting 1-phenylglyoxylic acid ethyl ester-2-acetylhydrazone (A) with hydrazine hydrate, or (b) reacting 1- phenyl - 1 - ethoxycarbonyl - 4 - chloro - 2,3- diaza-pentadiene (B) with hydrazine hydrate. By analoqous methods there may be obtained derivatives of the above triazin-5-one containing CH 3 , CF 3 , C2, C(CH 3 ) 3 , OCH 3 and NO 2 . Compound (A) may be obtained by reacting phenylglyoxylic acid ethyl ester with acetylhydrazine. Compound (B) may be obtained by reacting 1- phenylglyoxylic acid ethyl ester-2-acetylhydrazone with phosphorus pentachloride.
公开号:SU728687A3
申请号:SU731921921
申请日:1973-05-16
公开日:1980-04-15
发明作者:Драбер Вильфрид;Тиммлер Хельмут;Дикоре Карлфрид;Р.Шмидт Роберт;Ойе Людвиг
申请人:Байер Аг (Фирма);
IPC主号:
专利说明:

The invention relates to chemical means of controlling undesirable vegetation, and in particular to methods of controlling weeds by treating her or her biotope with a herbicide based on 3-methyl-4-amino-5H-6-phenyl-1, 2,4- triazin-5-she. There are known methods for controlling weeds by treating a BOB plant with a herbicide based on 3-methylthio-4-methyl-5H-6-phenyl-1, 2,4-triaine-5-one 1. or 3-methoxy-4-methyl-5H-6-phenyl-1, 2,4-triazin-5-one 2. Closest to that proposed by the active ingredient of the herbicide, which is treated crops, is 3-methylthio-4-amino -5H-6-phenyl-1, 2,4-triazin-5-one 13. However, known herbicides based on 6-phenyl-1,2,4-triazin-5-one derivatives exhibit phytotoxicity to cultivated crops and in because of the low selectivity of the action can not be used in crops of beets. The aim of the invention is to increase the efficiency of the method of weed control by searching for a herbicidal agent by means of -3-5 where the field has been harvested or harvested by her or her biotope 6-phenylmethyl-4-amino-5H-1, 2,4- triazinone General formula I. X - hydrogen, methyl, trifluorine in amounts of 0.0001 - 10%. The proposed compounds can be studied in a known manner by reacting acetyl hydrazis with a C-ketocarboxylic acid with its ester. Table 1 gives the physicochemical actuality of the common ground form I compounds used as a quality herbicide. Table 1
Compound A (known) s 3-methylthio-4-amino-5H-b-phenyl-1, 2,4-triazin-5-one, ° compound B (known); {3 methoxycarbonylaminophenyl) -N- (3-methylphenyl) carbamate.
Example 1: Dovskhodovaya processing.
The seeds of beet, galinsog, poMaiii; KH of sprocket, nettle, and m tlyka were sown in the soil, which, after 1 day, was treated at a dose of 2.5-5 kg / ha and
Pre-emergence treatment
later, 3 nad.were accounting of the herbicidal activity on a scale of 0 on a scale of 0 — no damage; 1 - notice plant growth; 2 - noticeable damage; 3 - severe damage and only 50% of shoots; 4 - only 25% of shoots; 5 - full of death of plants
The results of the results are presented in table 2.
Reference - compound A.
 T a b l and c a
Example 2. Post-harvest processing. Plants of Bwsyuga, Stovnik, Bristles, Glyce, Sorghum, Highlander, and Eziritsa 5–15 cm high were treated in a dose
Post-harvest processing
Table 1,2,4 kg / ha with compound 1,2,3 and standard - compound B. After 3 weeks. an account of herbicidal activity was carried out. On a scale. j The test results are presented in table 3 ,.
权利要求:
Claims (3)
[1]
1. Patent of the USSR 296303, cl. A 01 N 8/22, 08.18.67. 2. Patent of the USSR 254420,
[2]
cl. A 01 N 9/21, 04.16.66.
[3]
3. German patent 1542873, cl. 45 19/02, published. 12.06.70
类似技术:
公开号 | 公开日 | 专利标题
SU728687A3|1980-04-15|Weeds fighting method
SU610470A3|1978-06-05|Method of fighting undesirable vegetation
SU1223827A3|1986-04-07|Method of fighting undesirable plants
SU646875A3|1979-02-05|Plant growth regulator
RU2029471C1|1995-02-27|Pyrimidine derivatives, herbicide composition, and a method of struggle against weed using composition
US3869278A|1975-03-04|Hydroxylamines and derivatives thereof as abscission agents
SU1169516A3|1985-07-23|Method of fighting undesirable plants
US4115095A|1978-09-19|5-Aryl-1,2,4-thiadiazole-3-carboxylates and agricultural methods
SU493056A3|1975-11-25|Herbicidal composition
US3268323A|1966-08-23|Method for regulating plant growth
SU415847A3|1974-02-15|HERBICIDE
SU579847A3|1977-11-05|Herbicide
SU694044A3|1979-10-25|Plant growth regulating composition
SU555825A3|1977-04-25|The way to combat unwanted vegetation
US3932458A|1976-01-13|Antimicrobial and plant-active 4,5-dihalopyrrole-2-carbonitriles
SU978712A3|1982-11-30|Herbicidal preparation
US3985539A|1976-10-12|4,5-Dihalopyrrole-2-carbonitrile-containing terrestrial and aquatic hebicidal composition
SU461485A3|1975-02-25|Herbicidal composition
SU415845A3|1974-02-15|HERBICID12
SU507202A3|1976-03-15|Herbicidal composition
SU1209018A3|1986-01-30|Method of controlling weeds
SU625577A3|1978-09-25|Herbicide
SU1111673A3|1984-08-30|Method for controlling wild plants
SU843696A3|1981-06-30|Herbicidic composition
SU465766A3|1975-03-30|Herbicide
同族专利:
公开号 | 公开日
ES414824A1|1976-02-01|
FR2185034A1|1973-12-28|
IT987656B|1975-03-20|
CS174882B2|1977-04-29|
HU166183B|1975-02-28|
TR17273A|1975-03-24|
GB1368416A|1974-09-25|
IE37643L|1973-11-18|
FR2185034B1|1977-02-11|
DE2224161A1|1973-11-29|
DD104019A5|1974-02-20|
YU39297B|1984-10-31|
JPS5626644B2|1981-06-19|
AT327607B|1976-02-10|
NL7307004A|1973-11-20|
ATA820174A|1975-04-15|
PL89244B1|1976-11-30|
AT325341B|1975-10-10|
BE799584A|1973-11-16|
IL42271D0|1973-07-30|
IE37643B1|1977-09-14|
IL42271A|1976-10-31|
JPS4954537A|1974-05-27|
NL177461C|1985-10-01|
YU128373A|1982-05-31|
NL177461B|1985-05-01|
CH581951A5|1976-11-30|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题

DE2107757C3|1971-02-18|1980-02-28|Bayer Ag, 5090 Leverkusen|4-Amino-1,2,4-triazin-5-ones, process for their preparation and their use as herbicides|
BE786840A|1971-07-29|1973-01-29|Bayer Ag|PROCESS FOR PREPARING 1,2,4-TRIAZINE -5-ONES|DE2346936C2|1973-09-18|1982-05-06|Bayer Ag, 5090 Leverkusen|Process for the preparation of new 3,4-dihydro-1,2,4-triazines and three compounds of this type and their use|
DE2537290A1|1975-08-21|1977-03-03|Bayer Ag|Means for selective weed control in turnips|
FR2482421B1|1980-05-19|1985-08-02|Slovenska Akademia Vied|AGENT FOR INCREASING THE HARVEST OF AGRICULTURAL PRODUCTS|
DE3102318A1|1981-01-24|1982-08-26|Bayer Ag, 5090 Leverkusen|METHOD FOR PRODUCING 3,6-DISUBSTITUTED 4-AMINO-1,2,4-TRIAZINE-5-ONES|
DE3206234A1|1982-02-20|1983-09-29|Bayer Ag, 5090 Leverkusen|SELECTIVE BEET HERBICIDE CONTAINING METAMITRON IN COMBINATION WITH A NAPHTHOCHINONE DERIVATIVE|
JPS6076640U|1983-10-31|1985-05-29|
JPS60120908U|1984-01-26|1985-08-15|
JPH0417476Y2|1986-12-27|1992-04-20|
EP0549531A1|1991-12-20|1993-06-30|Säurefabrik Schweizerhall|Process for preparing acid anhydrides|
DE4313093C2|1993-04-22|1996-01-11|Stefes Pflanzenschutz Gmbh|Suspension concentrates containing metamitron based on water as the only carrier|
DE4329974A1|1993-09-04|1995-03-09|Stefes Pflanzenschutz Gmbh|Aqueous herbicidal suspension concentrates|
DE19605786A1|1996-02-16|1997-08-21|Hoechst Schering Agrevo Gmbh|Oil suspension concentrates|
DE10143084A1|2001-09-03|2003-03-20|Bayer Cropscience Ag|Fruit thinning process|
EP2052610A1|2007-10-24|2009-04-29|Bayer CropScience AG|Herbicide combination|
DE102008037630A1|2008-08-14|2010-02-18|Bayer Cropscience Ag|Herbicidal combination, useful to control undesired plant growth in plant culture e.g. wheat, comprises dimethoxytriazinyl-substituted difluoromethanesulfonyl anilide compounds and herbicides comprising triazine compounds e.g. ametryn|
EP2238834A1|2009-04-07|2010-10-13|Bayer CropScience Aktiengesellschaft|Defoliant based on thidiazuron and 1,2,4-triazinones|
法律状态:
优先权:
申请号 | 申请日 | 专利标题
DE19722224161|DE2224161A1|1972-05-18|1972-05-18|SELECTIVE HERBICIDAL AGENTS|
[返回顶部]